Iridia wasn't just a Core, it was that Civilization's homeworld/capital.
Poaching should not work on homeworlds, as the "Governor" of the homeworld is the Civilization's Leader. On a flavor note, it would make little sense for you to employ the leader of the Civilization you were just at war with. As to game balance, Civilization Leaders have some pretty powerful buffs and that would make this a little over-powered.